25: Manganese--which is unrelated to magnesium--is not one of our planet's better-known metals. Yet, it's only behind iron, aluminum, and copper when it comes the amount that man uses. Manganese itself is hard, brittle, and rusts easily. But as an alloy, it makes steel harder without becoming more brittle and inhibits rusting. The steel industry consumes almost 90 percent of the world's manganese production.
Manganese (Mn) is a key component in steel and iron production and also plays an important role in stainless steel and aluminum alloys. It is the glue that binds, hardens and prevents iron and steel products from being too brittle.
Manganese compounds are added to gasoline to boost octane and reduce engine knocking. It is used in benzylic alcohols, rust and corrosion prevention, paint, batteries, animal feed, glass production, fertilizers and medical applications.
And, it's a trace nutrient essential to all life forms. There really is no suitable substitute for manganese. And when nickel is expensive, some steel manufacturers will substitute with manganese.
Access: For obvious reasons, the U.S. has long considered manganese a strategic metal. Yet, we weren't blessed with much of it. There has been no domestic production since 1985, and the recent plunge in prices hasn't helped ongoing efforts to develop any production here.
Over three-quarters of the world's known manganese reserve base is in South Africa. The majority of the reserves which can be economically developed are in South Africa and the Ukraine. Before WWII, the other major sources of the metal were Brazil, India and Ghana, with the latter two being British territories until 1947 and 1957, respectively. From this link...
Following World War II and the beginning of the "Cold War," the Soviet Union embargoed the shipment of manganese ore to the United States, traditional sources of manganese began to be depleted, and the development of new sources became a major strategic objective of Western governments.
During this period major new mines were developed in Brazil and Mexico by a major American steel company, in Gabon by a French/American consortium, and in Australia by an Australian steel company. Development of the Black Rock mine in the Kalahari region of South Africa led to the discovery of other deposits in the area, and finally to the recognition of the full potential of the Kalahari district.
For years, the U.S. stockpiled manganese in case of a major supply interruption. Finally as new production came on line, the U.S. began selling off that stockpile in the mid-'60s. Little wonder the price of manganese dropped considerably. Using inflation-adjusted dollars, manganese has never exceeded its peak price in 1957, even with the spike during the recent commodity bubble. Today we get just over half of our manganese from South Africa and Gabon.
FYI, the are lots of magnesium nodules on the deep ocean floor, but at this point it's not economical to recover them.
Manganism: There's been manganese mining in various parts of Mexico's State of Hidalgo since 1960. Minera Autlán doesn't believe it's at fault for the following.
With Riojas at the head of an interdisciplinary group that included the government's National Institute of Neurology, the INSP over the past decade measured the presence of manganese in the air, water supplies, soil, homes and roads near the mines, which are both open-pit and underground operations.
In 2002 and 2003, blood and hair samples were taken from 300 adults and subjected to a variety of medical tests. In 2007, the same studies were carried out for 300 children between the ages of seven and 11. One part of the samples came from residents of areas near the mines, and the rest from residents of places similar in terms of social and economic development, but not near manganese mines.
Riojas said the findings are alarming. Sixty percent of the adults who live near the mines present neurological problems and trembling similar to the effects of Parkinson's disease. In the case of the children near the mines, it was found that their intellectual and learning abilities are 20 percent lower than the comparable group that does not live near any mines.
Manganism--poisoning from long-term exposure to manganese (end of previous blog here)--was first identified way back in 1837. From this link...
Manganism occurs when too much manganese injures the part of the brain that controls body movements. This exposure occurs primarily through inhalation. Although some of the symptoms of manganism can be treated with drugs and therapy, the damage that occurs to the brain is permanent.
In the industrialized world, exposure is more often due to welding, though some pesticides and batteries are also culprits. Rather than wading through the legal and scientific battles over liability, this link points towards interesting reading on the subjects. But note that manganism and Parkinsonism, while presenting some similar symptoms, are different dysfunctions. Manganism also shares some symptoms with Lou Gehrig's disease and multiple sclerosis. Misdiagnosis of "welding disease" is an issue.
Regular Showers: The EPA has a limit for manganese in drinking water. However, it's a secondary standard, meaning it's related to things like taste, odor, and aesthetics, not health. That makes it a recommendation, not a requirement...though most communities do treat for it if levels are high. Note that this is rarely an issue when using surface water...unless for instance there's been a major coal ash spill.
It's usually people living on wells who may be using water high in manganese. Sometimes that water gives a hint by either staining or stinking. As with iron, under certain conditions manganese can stain one's laundry--usually brown or black splotches. And also as with iron, one of several reasons that well water can smell of rotten eggs is otherwise-harmless bacteria dining upon the manganese and producing hydrogen sulfide as a waste product.
So, does manganese in our drinking water present a health risk? When reading the following, bear in mind that "rodents do not provide a good experimental model for manganese neurotoxicity."
A new analysis based on animal studies suggests that showering in manganese-contaminated water for a decade or more could have permanent effects on the nervous system. The damage may occur even at levels of manganese considered safe by the Environmental Protection Agency, according to researchers from Wake Forest University School of Medicine.
...
“Inhaling manganese, rather than eating or drinking it, is far more efficient at delivering manganese to the brain,” said Spangler. “The nerve cells involved in smell are a direct pathway for toxins to enter the brain. Once inside these small nerves, manganese can travel throughout the brain.”
Elsner and Spangler extrapolated data from rodents to estimate human exposure to manganese during showering. They found that after 10 years of showering in manganese contaminated water, children would be exposed to doses of manganese three times higher than doses that resulted in manganese deposits in the brains of rats. Adults would be exposed to doses 50 percent higher than the rodents.
The EPA published a health advisory for manganese back in 2004. It notes that the secondary standard for manganese is 0.05 milligrams per liter, which is well below the 0.3 milligram per liter lifetime health advisory value that "will protect against concerns of potential neurological effects."
School Air: USA TODAY published a report earlier this month on the air quality around our nation's schools. From this link...
USA TODAY gathered information on about 127,800 public and private schools from the National Center for Education Statistics and more than two dozen state education agencies. While we attempted to make the list as comprehensive as possible, it may not include some recently opened buildings. It also includes some schools that have closed since 2005. We also excluded some schools whose locations we could not map.
The database lists the carcinogens and other toxic chemicals that cause most of the air quality problems. At some schools, manganese and manganese compounds are a culprit. It defines them as follows:
Manganese is used to produce pesticides, batteries, and other industrial products. Although trace elements are found in food and are considered essential for good health, overexposure for long periods can cause mental and emotional disturbances and slow and clumsy body movements--a disease of the brain caused manganism. Children are more vulnerable to such exposures than adults. EPA says that it cannot be determined if there is a link between manganese and cancer.
I looked up the nearest high school (North Valley in Merlin) and found it was in the 78th percentile in the nation--which is better than average. The two toxins noted were formaldehyde (72%) and acetaldehyde (12%). The three polluters supposedly most responsible for the toxics were:
- Roseburg Forest Products Co Riddle Plywood #4 (Riddle OR)
- Timber Products Co Medford (Medford OR)
- Sierrapine Ltd. Medite Div. (Medford OR)
There's no way that those volatile organic compounds came from that far away. But for instance, both are found in auto exhaust and cigarette smoke, and formadehyde is used in several industrial applications. North Valley HS is near the interstate, an industrial park, the little county airport, etc.
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